Jan Czochralski was born on 23 October 1885 in Kcynia, which was
then under the Prussian domination. He was the eight child of
Franciszek and Marta Czochralski. He started the education at
teachers' seminar in Kcynia. He was mostly interested in chemistry
during his school days. After graduating the school he moved to
Krotoszyn, to work in a drugstore and to study chemistry on his
own. Later, he moved to Berlin and in 1904 began to work in the
pharmacy and drugstore of Dr. A. Herbrand in Altglienicke. He
carried out analyses of ores, oils, greases and metals. Then he
worked for a short period in the laboratory of Kunheim and Co. in
Niederschöneweide near Berlin and then in Allgemeine
Elektricitäts-Gesellschaft (AEG).
The job in Kabelwerk Oberspree and the two years spent in their
research laboratories prepared him to become head of the
laboratory of steel and iron research. This laboratory dealt with
the checking the quality and purity of metals and alloys and was
engaged in the refinement of copper. Simultaneously he attended
lectures on chemistry at the Charlottenburg Polytechnic near
Berlin. In about 1910 he obtained the title of chemist-engineer.
From 1911 to 1914 he was an assistant of Wichard von Moellendorff
with whom he published his first paper devoted to the
crystallography of metals, or more precisely to dislocation theory
("Technologische Schluesse aus Kristallographie der Metalle"
["Technological conclusions from metal crystallography"],
Zeitschrift des Vereines Deutscher Ingenieure 57, 931-935,
1014-1020 (1913).
The main task of Czochralski was the introduction of aluminium to
electrical engineering i.e. pioneering works on the technology of
the production of sheets, wires and pressings of aluminum, the
study of aluminum alloys, and standardisation of metallographic
studies. Metals and metallography became Czochralski's passion.
His achievements were outstanding and opened new roads in
metallurgical science and technology.
Discovery of the Czochralski Method
The Czochralski method of growing single crystals brought Jan
Czochralski his greatest publicity. The method was developed in
1916 and was initially used to measure of crystallisation rate of
metals. The method was developed as a result of an accident and
through Czochralski's careful observation. One evening he left
aside a crucible with molten tin and returned to writing notes on
the study carried out on a crystallisation study. At some moment,
lost in thoughts, instead of dipping his pen in the inkpot, he
dipped it in the crucible and withdrew it quickly. He observed
then a thin thread of solidified metal hanging at the tip of the
nib. The nib slot, in which crystallisation was initiated, was
replaced by a special narrow capillary and in some cases by a seed
of the growing crystal. Czochralski checked later that the
crystallised wire was a single crystal. The crystals obtained in
that way had diameters of about a millimetre and lengths up to 150
mm. Czochralski published a paper on the study of the rate of
crystallisation of tin, zinc and lead, and the maximum rate of
pulling of a crystal was recognised as the characteristics of the
crystallising material ("Ein neues Verfahren zur Messung des
Kristallisationsgeschwindigkeit der Metalle" ["A new method for
the measurement of crystallisation rate of metals"], Z. phys.
Chem. 92, 219-221 (1918); the paper was received in the editorial
office on 19 August 1916). Details of the new method, but without
any figure, appeared earlier in another paper published by
Czochralski: Zeitschrift des Vereines Deutscher Ingenieure 61,
345-351 (1917)). He is also the author of the first attempt at
creating a microscopic theory of recrystallization (Int.
Zeitschrift fuer Metallographie 8, 1-43 (116)). The application of
the Czochralski method exclusively as a technique for obtaining
single crystals is due to W. von Wartenberg (Verhandlungen der
Deutsche Phys. Gesellschaft 20, 113 (1918)). Thus, the Czochralski
method was a method of producing large single crystals by
inserting a small seed crystal into a crucible filled with molten
material, then slowly pulling the seed up from the melt with its
simultaneous rotation.
Later modifications of this method have also been reported. The
increasing demand for semiconductor electronic materials led the
Americans G.K. Teal and J.B. Little from Bell Telephone
Laboratories in Murray Hill, NY, to extend the Czochralski method
to the growing of nonmetalic materials, starting with germanium in
1948 (Growth of germanium single crystals, Phys. Rev. 78, 647
(1950)) and soon thereafter silicon. Teal's improvements gave this
growth method a world-wide fame as the Czochralski method for
growing large single crystals on an industrial scale. At the
present, no other crystal growth method can compete with the
Czochralski method.
In Frankfurt on Main
In 1917 Jan Czochralski moved to Frankfurt on Main and, combining
scientific research with workshop efforts, organized the
Laboratory of Metal Science of the Metallgesellschaft AG. Several
valuable scientific papers and patents were developed there. Among
the patents was the highly famous patent on a tin-free bearing
alloy for railways, called metal B, patented in 1924 and bought by
many countries all over the world, including USA, France and
England. He also pioneered investigations of the anisotropy of the
hardness of single crystals (works between 1913 and 1923), which
are of great importance for the plastic treatment of materials.
Czochralski wrote two handbooks: "Lagermetale und ihre
technologische Bewertung ["Bearing metal and its technological
evaluation"] (coauthored with G. Welter, 1920, 1924) and "Moderne
Metallkunde in Theorie and Praxis" ["Modern metal science in
theory and practice"] (1924), which were later translated into
several languages. Many of Czochralski's works were military
secrets (later even in Poland) and have never been published. It
is known, however, that during this Frankfurt period he authored
reports containing more than two thousand pages.
In 1919 Jan Czochralski with a few friends founded German Society
for Metals Science (Deutsche Gesellschaft für Metallkunde), and in
1925 became its president. He was also an honorary member of the
Institute of Metals in London.
In Poland Again
Poland revived after the First World War and required knowledge
and capabilities of its sons and daughters scattered all over the
world. Jan Czochralski did not forget about his native land
despite his high position in the German industry. He returned to
Poland at the invitation of the President of Poland, Ignacy
Moscicki, an eminent professor of chemistry, and in 1929 he took
the position of a professor in the Faculty of Chemistry at the
Warsaw University of Technology, where he also obtained the
honorary doctorate. He invested the fortune he brought from
Germany in Polish industry and arts (i.e. founded artistic
scholarships). The drawing rooms of his home became popular in
Warsaw. Once again he organised his scientific workshop:
Department of Metallurgy and Metals Science in the Warsaw
University of Technology and Institute of Metallurgy and Metal
Science. The latter mainly worked for the Ministry of Defence.
Both of these scientific institutions were equipped with the
latest apparatus. Prof. Czochralski also organized Metallurgical
Section in the Chemical Research Institute, one of the leading
independent research institutions in the country. In the
institutions mentioned above, Prof. Czochralski continued the
studies, which he undertook earlier in Germany. He was still
engaged in measurements of the rate of crystallisation of metals.
He also studied the elastic properties of metals and alloys and
their corrosion in different gas atmospheres. In addition,
Czochralski investigated the influence of experimental conditions
on the shape of crystals obtained by his growth method
("Wiadomosci Instytutu Metalurgii i Metaloznawstwa" 3, 69-74
(136); 85-88 (1937)) and studied another method of obtaining
single crystals, by recrystallization of initial material.
The list of publications by J. Czochralski contains about one
hundred papers. A complete list of these papers may be found in
Wiadomości Chemiczne 41, 597 (1987) or in his biography by P.
Tomaszewski ("Jan Czochralski and his method", Wroclaw-Kcynia
2003). He was very interested in everything that concerned his
native surroundings. He supported both archeological studies as
well as the geological search for petroleum beds. He was also
interested in the progress of Polish economy and there are even
some papers retained from that period.
The Tragedy of War
In the winter of 1939 at the beginning of the II World War, Jan
Czochralski Czochralski organized the Department of Materials
Research as a service institution. This was at the request of his
co-workers from the Warsaw University of Technology closed by
Germans. At the price of producing spare parts for the Germans and
the city self-government administration, the service institution
provided jobs and security (giving appropriate documents) to dozen
of persons in occupied Warsaw. It also supplied the Underground
National Army fighting for the freedom of the country.
Co-operation with the Underground National Army (for example,
extracting persons imprisoned by the Germans, helping the Jewish
ghetto in Warsaw, saving collections from destroyed museums, and
rendering help to Polish men of letters and artists) was the
natural feature of the activities of Czochralski. He considered it
his moral duty to use his German connections and a good knowledge
of the German language for the Polish cause, risking both being
imprisoned by the Germans and/or being suspected of collaboration.
Return to Kcynia
After the war Professor Czochralski decided to return to native
Kcynia. With his family he founded there a drug company, BION,
producing different types of cosmetics and household chemicals. In
this way the circle closed. Jan Czochralski returned to Kcynia and
to the chemistry of drugs and pharmacy. On April 22, 1953 he died
of heart disease and was buried in Kcynia.
Reference
P. Tomaszewski "Jan Czochralski and His Method" ed. ATUT and
INTiBS PAN, Wroclaw-Kcynia 2003 (ISBN 83-906218-2-7 and ISBN
83-89247-27-5).